Group E
Two goals from Ivan Rakitic saw Barcelona defeat BATE Borisov 2-0 at the Borisov Arena.
The Catalan giants maintain their unbeaten start in their European campaign as they extended their lead to three points at the top of the table.
While fans inside the BayArena were treated to an eight-goal thriller as Bayer Leverkusen drew 4-4 with Roma.
The German side raced into a two-goal lead inside 20 minutes but eventually needed two goals in the final 10 minutes to rescue a point.
Former Manchester United striker Javier Hernandez scored twice for the hosts while Danielle De Rossi scored a brace for the Serie A side.
Group F
Arsenal recorded their first win of the campaign as they defeated Bayern Munich 2-0.
Goals from Olivier Giroud and Mesut Ozil ensured Bayern's unbeaten start in Europe came to an end.
In the other game Olympiakos recorded a 1-0 away victory over Dinamo Zagreb as former West Brom striker Brown Ideye grabbed the winner.
Group G
Chelsea endured a goalless draw against Dynamo Kiev as Jose Mourinho blasted the referee "weak and naive."
The English side hit the woodwork twice and had a strong penalty appeal turned down.
Porto recorded a comfortable 2-0 victory over Israeli side Maccabi Tel Aviv with goals coming from Vincent Aboubakar and Yacine Brahimi.
Group H
Spanish side Valencia defeated AA Gent 2-1 at the Mestalla Stadium.
Lasse Nielsen's own goal had given the home side the lead before Thomas Foket equalised for the visitors.
But Stefan Mitrovic's goal ensured Valencia left with all three points.
Zenit St Petersburg defeated French side Lyon 3-1 on home soil with goals coming from Artem Dzyuba, Danny and a brilliant long-range strike by Hulk.
Alexandre Lacazette scored for the Ligue 1 outfit.
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